(Ir[4-t-Bu-Phenyl-4-t-Bu-Py]2(dtbpy))PF6 - Names and Identifiers
Name | Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)
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Synonyms | Ir(dtbppy)2(dtbbpy)PF6 (Ir[4-t-Bu-Phenyl-4-t-Bu-Py]2(dtbpy))PF6 )-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethyL Bis [2- (4-tert-butylphenyl) -4-tert-butylpyridine] [2,2'-bis (4-tert-butylpyridine)] iridium (III) hexafluorophosphate Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir(DTBPPY)2(DTBBPY)PF6 Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)
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CAS | 808142-80-5
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(Ir[4-t-Bu-Phenyl-4-t-Bu-Py]2(dtbpy))PF6 - Physico-chemical Properties
Molecular Formula | C56H72F6IrN4P
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Molar Mass | 1138.4 |
Appearance | Powder |
Color | yellow |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
Sensitive | air sensitive |
(Ir[4-t-Bu-Phenyl-4-t-Bu-Py]2(dtbpy))PF6 - Risk and Safety
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
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TSCA | No |
(Ir[4-t-Bu-Phenyl-4-t-Bu-Py]2(dtbpy))PF6 - Introduction
Iridium(1 ),[4,4 '-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN] a compound with the following properties (hexafluorophosphate)-κC:
1. Appearance: Iridium (1) complex is a yellow solid.
2. Chemical properties: It is stable in the air, insoluble in water, but soluble in organic solvents such as ethanol and dimethylformamide.
3. use: the complex is commonly used in organic light-emitting diodes and solar cells and other electronic devices as a luminescent material. It can also be used in fields such as photoelectric conversion and catalysts.
4. Preparation method: preparation of iridium (1) complexes is generally obtained by complexation reaction. The specific method is to react iridium ion with ligand [4,4 '-bis (1,1-dimethylethyl)-2,2'-bipyridyl-k N1,k N1 '] bis [5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridyl-k N] phenyl-k C], and then react with hexafluorophosphoric acid to form a complex.
5. Safety Information: The effects of this compound on human health and the environment have not been fully established. In the use and handling, should take appropriate protective measures, avoid contact with skin and eyes, pay attention to protect the respiratory system. In case of contact, rinse immediately with plenty of water and seek medical advice.
Last Update:2024-04-09 02:00:49